The US on Friday signalled it was ready to step up economic measures to try to drive Venezuelan President Nicolas Maduro from power as some US diplomats left the embassy in Caracas and Russia vowed to back its socialist South American ally.

The US treasury department stopped short of announcing a freeze on Venezuela’s US assets and accounts, but said it would take steps to ensure commercial transactions were “consistent” with its recognition this week of Opposition leader Juan Guaido as Venezuela’s legitimate head of state.

US secretary of state Mike Pompeo on Saturday will urge members of the UN Security Council to recognise Guaido. Washington requested the meeting of the 15-member council after a string of countries threw their weight behind Guaido, who heads Venezuela’s congress, and urged Maduro to step down.

Pompeo will be accompanied by former US diplomat Elliott Abrams, who he named on Friday to lead US efforts on Venezuela. Abrams is a neoconservative who has long advocated an activist US role in the world.

Russia opposes the US efforts and has accused Washington of backing a coup attempt, placing Venezuela at the heart of a growing geopolitical duel.

Private military contractors who carry out secret missions for Russia have flown into Venezuela in the past few days to beef up security for Maduro, sources said.

Maduro said he welcomed the UN debate. “Thanks, Mike,” he said, tongue in cheek, during a Friday news conference. “We’re going to tell the truth about the articles of the Constitution, about the coup.”

Maduro on Wednesday ordered US diplomats out of the country within 72 hours. On Friday, some American diplomats left the US embassy in Caracas in a convoy of vehicles with a police escort en route to the airport, according to a Reuters witness.

UN human rights boss Michelle Bachelet called on Friday for an investigation into alleged excessive use of force by Venezuelan security forces against anti-Maduro protesters in recent days, adding that she was “extremely concerned” that the situation could rapidly spiral out of control.

Guaido, who has galvanised Venezuela’s Opposition, proclaimed himself interim President on Wednesday during a march of hundreds of thousands in Caracas. He is considering making a request for funds from international institutions including the IMF, sources said on Friday.

However, he still has no control over the Venezuelan state and the military, which has so far remained loyal to Maduro despite a deep economic and political crisis that has sparked mass emigration, with inflation forecast to rise to 10 million per cent this year.

Guaido has promised future amnesties to military members if they disavow Maduro, asking soldiers on Friday to “put themselves on the side of the Constitution.”

Most Latin American nations have joined the US in supporting Guaido’s claim on the presidency, although Mexico’s new Leftist government has said it would not take sides. Mexican President Andres Manuel Lopez Obrador said on Friday his administration would be willing to mediate.

Guaido said he would reject any negotiations that did not include Maduro's exit, the setting up of a transition government, and free elections to pick a new President.

“No one wants fake dialogue ... the only thing we want to negotiate is the end of the usurpation,” he told a crowd clustered in a plaza in Caracas’ Chacao district.